中文名称：3-氧-苄基-1,2:5,6-二-氧-异亚丙基-α-D-呋喃葡萄糖苷
  • 3-氧-苄基-1,2:5,6-四-氧-异亚丙基-α-D-呋喃葡萄糖苷; 3-O-苄基-1,2:5,6-O-二异丙叉-ALPHA-D-呋喃葡萄糖
  • 3-O-Benzyl-1,2,5,6-di-O-isopropylidene-alpha-D-glucofuranose
  • 3-(2,2-dimethyl-1,3-dioxolan-4-yl)-7,7-dimethyl-4-phenylmethoxy-2,6,8- trioxabicyclo[3.3.0]octane; 6-(benzyloxy)-5-(2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxole (non-preferred name); 3-O-Benzyl-1,2; 5,6-di-O-isopropylidene-α-D-glucofuranose; 1,2:5,6-bis-O-(1-methylethylidene)-3-O-(phenylmethyl)-a-D-Glucofuranose; 1,2:5,6-di-O-isopropylidene-3-O-benzyl-α-D-Glucofuranose; 3-O-benzyl-1,2:5,6-di-O-isopropylidene-D-Glucofuranose
  • 18685-18-2
  • C19H26O6
  • 350.4061
  • InChI=1/C19H26O6/c1-18(2)21-11-13(23-18)14-15(20-10-12-8-6-5-7-9-12)16-17(22-14)25-19(3,4)24-16/h5-9,13-17H,10-11H2,1-4H3
  • 3-氧-苄基-1,2:5,6-二-氧-异亚丙基-α-D-呋喃葡萄糖苷 18685-18-2
  • 1.21g/cm3
  • 422.6°C at 760 mmHg
  • 168.3°C
  • 5.85E-07mmHg at 25°C

  • 性 状：本品为黄色至酒红色粘稠状液体。溶于乙醇、乙酸乙酯、二氯甲烷、氯仿和乙醚等，不溶于水。

  • 用 途：本品是重要的药物原料和中间体，主要用于抗肿瘤活性物Goniofufurone，脑瘤抑制剂2-脱氧-2,2-二氟-D-吡喃阿拉伯糖，寡核苷酸前体(9-(3′-O-苄基-2′-O-苄氧羰基) β-D-呋喃木糖基)腺嘌呤，糖苷酶抑制剂野尻霉素，抗HIV活性物1,4-二脱氧-1,4-亚胺基-D-阿拉伯糖醇，抗菌消炎活性物糖基吲哚、(−)-Dinemasone B、磷脂酰肌醇甘露糖苷类似物，具有多种药理活性的糖基海星皂苷等的合成。也用于合成1,3-β-匍聚六聚糖疫苗、磺达肝葵钠和羟硝氨糖环素的中